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. Author manuscript; available in PMC: 2013 Sep 26.
Published in final edited form as: J Am Chem Soc. 2012 Sep 14;134(38):15696–15699. doi: 10.1021/ja307501e

Scheme 1. Chemo-enzymatic synthesis of C-9 N-acyl modified sialoside analogues.a.

Scheme 1

aReagents and conditions: a) CMP-9-NH2-Neu5Ac, PmST1; b) RC(O)NHS, THF, H2O (1-9, see Table 1 for R).