Table 2. The chemical contents of six species of beetle elytral surfaces including atom content (a. c.), binding energy (b. e.) and valence state (v. s.) of elements.
Elements | ChemicalContent | Species | |||||
A. kulzeri | Anomala sp. | C. molossus | S. macrocnemia | A.sinica | H.dauricus | ||
C1s | a. c. | 73.09 | 83.11 | 84.08 | 80.31 | 80.74 | 80.07 |
b. e. | 284.8 | 284.83 | 284.81 | 284.83 | 284.77 | 284.81 | |
v. s. | C-C, C-H | C-C, C-H | C-C, C-H | C-C, C-H | C-C, C-H | C-C, C-H | |
O1s | a. c. | 17.09 | 12 | 9.87 | 13.09 | 12.54 | 13.24 |
b. e. | 531.82 | 532.23 | 531.74 | 532 | 531.94 | 531.44 | |
v. s. | O-S | O-S | O-H, O-S | O-S | O-S | O-H, O-S | |
N1s | a. c. | 6.31 | 2.35 | 2.04 | 2.96 | 4.23 | 4.88 |
b. e. | 399.9 | 400.1 | 400.28 | 399.97 | 399.83 | 400.9 | |
v. s. | N-C | N-C | N-C | N-C | N-C | N-C | |
Si2p | a. c. | 1.02 | 1.2 | 2.19 | 1.9 | 0.88 | 0.86 |
b. e. | 102.29 | 102.14 | 101.89 | 102.04 | 101.91 | 102.03 | |
v. s. | Si-O, Si-N | Si-O, Si-N | Si-C | Si-O, Si-N | Si-C | Si-C | |
Ca2p | a. c. | 1.07 | 0.51 | 1.81 | 0.59 | 0.46 | – |
b. e. | 347.38 | 347.19 | 347.3 | 347.37 | 347.1 | – | |
v. s. | Ca-O | Ca-O | Ca-O | Ca-O | Ca-O | – | |
P2p | a. c. | 0.44 | 0.65 | – | 0.5 | 0.47 | 0.42 |
b. e. | 133.55 | 133.4 | – | 133.47 | 133.23 | 133.36 | |
v. s. | P-O | P-O | – | P-O | P-O | P-O | |
S2p | a. c. | 0.39 | 0.18 | – | 0.35 | 0.37 | – |
b. e. | 168.2 | 168.26 | – | 167.92 | 168.22 | – | |
v. s. | S-C, S-O | S-C, S-O | – | S-C, S-O | S-C, S-O | – | |
Na1s | a. c. | – | – | – | – | 0.31 | 0.53 |
b. e. | – | – | – | – | 1071.07 | 1070.83 | |
v. s. | – | – | – | – | Na-O | Na-N | |
Al2p | a. c. | 0.59 | – | – | 0.3 | – | – |
b. e. | 74.3 | – | – | 73.74 | – | – | |
v. s. | Al-O | – | – | Al-O | – | – |
Footnote: A dash (–) indicates the elements on the elytral surfaces are absent.