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. 2012 Apr 23;109(39):15663-15668. doi: 10.1073/pnas.1118333109

Fig. 2.

Fig. 2.

Schematic depiction of the states and charge transfer reactions involved in the proton-coupled electron transfer process of interest, corresponding to the bracketed steps in Fig. 1. The complex shown has methyl substituents on the P and N atoms with all rings in the boat conformation. The ET, PT, and EPT reactions are shown for H2 oxidation, (1a) → (2b), and H2 production, (2b) → (1a).