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. Author manuscript; available in PMC: 2012 Oct 10.
Published in final edited form as: Angew Chem Int Ed Engl. 2011 Sep 12;50(42):9943–9947. doi: 10.1002/anie.201104361

Table 1.

Ligand Evaluation[a]

graphic file with name nihms-368824-t0005.jpg
Entry Ligand Conv. of 1a [%][b] Yield of 2a [%][b] Yield of 2a’ [%][b]
1 L1 100% 26% 54%
2 L3 100% 20 63%
3 L4 100% 70% 19%
4 L5 70% trace 61%
5 L6 67% 3% 43%
6 L7 100% 66% 26%
7 L8 100% 64% 28%
8 L9 100% 57% 32%
9 L10 100% 54% 31%
[a]

Reaction conditions: 4-chloroanisole (1.0 mmol), 2-BuOH (2.0 mmol), (allyIpdcI)2 (1 mol %), Ligand (3 mol %), Cs2CO3 (1.5 mmol), 4Å molecular sieves (200 mg), Bu3N (1 ml), 90 °C, 21 h.

[b]

Determined by GC.