Skip to main content
. Author manuscript; available in PMC: 2013 Oct 8.
Published in final edited form as: Chemphyschem. 2012 Jul 6;13(14):3350–3356. doi: 10.1002/cphc.201200375

Table 2.

Sensitivity to polarity[a]

Slope Y-int. Slope Y-int. R2

cm−1/kcal mol−1 cm−1 - kcal mol−1
1a 93.7 2548 0.268 7.29 0.99510
8a 63.8 5188 0.182 14.83 0.86159

1b 75.4 4290 0.216 12.27 0.84211
8b 79.5 4437 0.227 12.69 0.96922
[a]

Polarity sensitivity equals the slope of the linearized Stokes shift vs. ET(30) plot. Values for 5-(thiophen-2-yl)-2dU 8a and 5-(fur-2-yl)-2dU 8b in cm−1/kcal mol−1 have been reported.[7, 25] A unitless value for polarity sensitivity is obtained by conversion of the Stokes shift value from cm−1 to kcal mol and replotting it as a function of the sample ET(30) value (in kcal mol−1). The adjusted R2 represents the goodness of the linear fit.