Table 1.
substrate | catalyst | Time (h) | conversion (%) | yield (%)b |
---|---|---|---|---|
PhCHO | 10 | 1 | 100 | 91 |
PhCHO | 18 | 1 | 100 | 92 |
PhCHO | 8 | 1 | 100 | 90 |
PhCOCH3 | 10 | 20 | 99 | 80 |
PhCOCH3 | 18 | 24 | 97 | 83 |
PhCOCH3 | 8 | 20 | 99 | 83 |
Conditions: [substrate] = 0.30 M, [catalyst] = 0.0060 M, p(H2) = 3 atm, in toluene at 25 °C.
isolated yield.