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. Author manuscript; available in PMC: 2013 Jan 1.
Published in final edited form as: Organometallics. 2011 Oct 21;31(7):2631–2638. doi: 10.1021/om2007453

Table 1.

Hydrogenation of Carbonyls Catalyzed by Ruthenium Hydrides 10 and 18 and by Iron Hydride 8.a

substrate catalyst Time (h) conversion (%) yield (%)b
PhCHO 10 1 100 91
PhCHO 18 1 100 92
PhCHO 8 1 100 90
PhCOCH3 10 20 99 80
PhCOCH3 18 24 97 83
PhCOCH3 8 20 99 83
a

Conditions: [substrate] = 0.30 M, [catalyst] = 0.0060 M, p(H2) = 3 atm, in toluene at 25 °C.

b

isolated yield.