Skip to main content
. Author manuscript; available in PMC: 2013 Oct 1.
Published in final edited form as: Inorg Chem. 2012 Sep 19;51(19):10290–10299. doi: 10.1021/ic301278m

Table 1.

Selected bond lengths (Å) and angles (°) for complexes 1–3, 4b, 5ba, 6a, and 7a.
1 2 3 4b 5b 6 7
M1–M2 2.9117(4) 2.8104(4) 3.1365(9) 2.3820(4) 2.3978(7) 2.4265(17) 2.4377(7)
M1–M3 2.8665(4) 2.8542(4) 3.1045(11) 2.3796(4) 2.3886(7) 2.4272(18) 2.3368(7)
M2–M3 2.38650(4) 2.7960(4) 3.1371(10) 2.3965(5) 2.3702(7) 2.4274(18) 2.4385(7)
M1–N1 2.242(2) 2.200(1) 2.124(2) 2.089(2) 1.971(4) 1.988(7) 1.925(3)
M1–N2 2.207(2) 2.183(1) 2.144(2) 2.068(2) 1.999(3) 1.983(8) 1.921(3)
M2–N2 2.187(2) 2.181(1) 2.119(2) 1.979(2) 2.063(3) 1.992(7) 2.053(3)
M2–N3 2.212(2) 2.192(1) 2.139(3) 1.952(2) 2.042(4) 1.989(8) 2.042(3)
M3–N1 2.191(2) 2.188(1) 2.138(2) 1.956(2) 2.024(4) 1.981(7) 1.948(3)
M3–N3 2.187(2) 2.201(1) 2.124(2) 1.975(2) 2.026(3) 1.987(8) 1.984(3)
M1–N4 2.191(2) 2.206(1) 2.099(2) 2.085(2) 1.964(3) 2.174(9) 1.853(3)
M1–N5 2.172(2) 2.311(1) – 2.112(2) 1.979(4) 2.120(9) 2.060(3)
M2–N5 2.201(2) 2.300(1) 2.084(3) 1.994(2) 2.027(4) 2.108(9) 2.029(3)
M2–N6 2.189(2) 2.186(1) – 1.956(2) 2.060(4) 2.181(8) 2.053(3)
M3–N6 2.196(2) 2.304(1) 2.077(2) 1.958(2) 2.040(3) 2.173(9) 2.017(3)
M3–N4 2.214(2) 2.193(1) – 1.990(2) 1.993(4) 2.136(9) 2.185(3)
M1–L1 2.2074(18) 2.1649(15) 2.214(2) 2.2026(6) 2.2358(12) 2.253(3) –
M2–L2 2.1890(19) 2.1489(15) 2.213(3) 2.2298(6) 2.2277(12) 2.252(3) 2.2906(12)
M3–L3 2.1808(18) 2.1647(15) 2.248(4) 2.2309(6) 2.2271(13) 2.253(3) 2.2607(11)
M3–M1–M2 59.44(1) 59.15(1) 60.35(2) 60.44(1) 59.36(2) 60.02(5) 61.38(2)
M3–M2–M1 59.50(1) 61.21(1) 59.32(2) 59.73 (1) 60.13(2) 60.01(5) 61.35(2)
M2–M3–M1 61.06(1) 59.65(1) 60.33(2) 59.83(1) 60.51(2) 59.98(5) 57.27(2)
M2–N1–M3 82.49(6) 79.81(5) 93.50(9) 72.15(6) 73.35(12) 75.57(5) 74.30(11)
M1–N2–M3 80.80(6) 79.33(5) 94.73(10) 74.62(6) 70.87(11) 75.53(5) 74.29(11)
M1–N3–M2 80.09(6) 81.25(5) 94.77(10) 72.45(6) 72.80(11) 75.93(5) 75.76(11)
M2–N4–M3 80.56(6) 77.15(5) – 72.15(5) 73.11(12) 67.83(5) 70.59(11)
M1–N5–M3 83.60(6) 76.98(5) – 73.96(6) 72.24(12) 67.70(5) 69.95(11)
M1–N6–M2 80.94(6) 78.61(5) – 71.43(6) 72.91(12) 67.70(5) –
M–N–Mavg 81.43(7) 78.86(6) 94.33(11) 72.29(7) 72.55(13) 71.71(6) 72.98(12)
a

From representative molecule in asymmetric unit.