Selected ion mass spectra of methyl cinnimate (A),
methyl benzoate (B), and methyl salicylate (C) showing isotopic
enrichment from [13C1]Phe. Tobacco plants
were inoculated with TMV, held at 32°C for 96 h, shifted to
23°C for 6 h, and infiltrated with 1 mm
[13C1]Phe. The phenolics were then analyzed
by GC-MS 6 h after infiltration. Major ions are shown and
enrichment was determined by a shift in the mass to M+ 1.
Methylated structures are shown and the location of enrichment is
indicated with an asterisk.