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. Author manuscript; available in PMC: 2013 May 1.
Published in final edited form as: Chem Sci. 2012 May;3(5):1589–1593. doi: 10.1039/C2SC01134D

Scheme 1.

Scheme 1

Rh2(S-PTTL)3TPA catalyzed cyclopropanation of styrene derivatives with α-alkyl diazoesters

a The enantioselectivity with Rh2(S-PTTL)4 was the same as that observed for Rh2(S-PTTL)3TPA. b The dr with Rh2(S-PTTL)4 was only 83:17