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. Author manuscript; available in PMC: 2012 Nov 5.
Published in final edited form as: J Phys Chem B. 2011 Aug 31;115(38):11261–11268. doi: 10.1021/jp2049266

Table 1.

Results of Fitting Models to the Combined Data for Ovomucoid, Bsa, and Binary Mixturesa

model best fit SSR × 10−9 no. independent nonideality parameters best-fit parameter values
virial expansion 0.99 7b MO = 29 700
MB = 64 100
BOO = 10.8
BOOO = 49.7
BOB = 6.07
BOBB = 30.12
BBB = 15.9
BBBB = 48.4
BBO = (13.1)b
BBOO = 115
effective HS 1 1.72 2 MO = 29 800
MB = 63 600
veff,O = 1.18
veff,B = 1.70
effective HS 2 1.24 4 MO = 30 100
MB = 63 700
veff,O/O = 1.42
veff,B/O = 1.32
veff,O/B = 1.65
veff,B/B = 1.71
effective HS 3 1.03 4 MO = 29 700
MB = 63 000
veff,O = 1.41
veff,B = 1.74
veff,OB = 2.73
logKOB0=2.22
a

Subscripts in parameter names: O, ovomucoid; B, BSA. Values of Bij are given in units of cm3/g, values of Bijk in units of (cm3/g)2. Values of specific exclusion volumes are given in units of cm3/g, and values of equilibrium association constants are given in units of M−1.

b

BBO and BOB are not independent: BBO = BOB × MB/MO.