Table 1.
Results of Fitting Models to the Combined Data for Ovomucoid, Bsa, and Binary Mixturesa
model | best fit SSR × 10−9 | no. independent nonideality parameters | best-fit parameter values | |
---|---|---|---|---|
virial expansion | 0.99 | 7b | MO = 29 700 | |
MB = 64 100 | ||||
BOO = 10.8 | ||||
BOOO = 49.7 | ||||
BOB = 6.07 | ||||
BOBB = 30.12 | ||||
BBB = 15.9 | ||||
BBBB = 48.4 | ||||
BBO = (13.1)b | ||||
BBOO = 115 | ||||
effective HS 1 | 1.72 | 2 | MO = 29 800 | |
MB = 63 600 | ||||
veff,O = 1.18 | ||||
veff,B = 1.70 | ||||
effective HS 2 | 1.24 | 4 | MO = 30 100 | |
MB = 63 700 | ||||
veff,O/O = 1.42 | ||||
veff,B/O = 1.32 | ||||
veff,O/B = 1.65 | ||||
veff,B/B = 1.71 | ||||
effective HS 3 | 1.03 | 4 | MO = 29 700 | |
MB = 63 000 | ||||
veff,O = 1.41 | ||||
veff,B = 1.74 | ||||
veff,OB = 2.73 | ||||
|
Subscripts in parameter names: O, ovomucoid; B, BSA. Values of Bij are given in units of cm3/g, values of Bijk in units of (cm3/g)2. Values of specific exclusion volumes are given in units of cm3/g, and values of equilibrium association constants are given in units of M−1.
BBO and BOB are not independent: BBO = BOB × MB/MO.