. Author manuscript; available in PMC: 2013 Sep 17.

Published in final edited form as: Inorg Chem. 2012 Sep 5;51(18):9598–9609. doi: 10.1021/ic300202f

Table 1.

Concentrations of all ions and, wherever appropriate, solvent medium in mol·dm⁻³ of the vanadium solutions studied by LAXS (L) and EXAFS (E), including their densities ρ, linear absorption coefficient μ, and label. xs denotes excess solvent

Sample	[V_tot]	[Cl⁻]	[ClO₄⁻]	[SO₄²⁻]	[solvent]	ρ/g·cm⁻³	μ/cm⁻¹	pH	Note
V³⁺ in water, pH=0.6	0.50	1.50	0.10		xs			0.60	E, L0
V³⁺ in water, pH=1.2	0.50	1.50	0.10		xs			1.22	E, L0_hyd
VO²⁺ in water	1.228		2.556		53.228	1.273	4.123	0.53	L, L1a
VO²⁺ in water	4.433		8.866		11.512	1.386	10.880	0.4	L, L1b
VO²⁺ in water	0.70		1.40		xs			0.5	E, L1c
VO²⁺ in dmso	0.369		0.738		13.282	1.136	5.460		L, L2a
VO²⁺ in dmso	0.18		0.36		xs				E, L2b
VO²⁺ in dmpu	0.18		0.36		xs				E, L3
VO₂⁺ in water	1.833			7.237	32.953	1.449	6.181	<0	L, L4a
VO₂⁺ in water	0.87			3.435	xs			<0	E, L4b
VO₂⁺ in dmso	1.374		3.822		11.693	1.401	7.503		L, L5a
VO₂⁺ in dmso	0.50		0.50		xs				E, L5b
VO₂⁺ in dmpu	0.20		0.20		xs				E, L6