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. Author manuscript; available in PMC: 2013 Oct 19.
Published in final edited form as: Org Lett. 2012 Oct 9;14(20):5314–5317. doi: 10.1021/ol302494n

Scheme 3.

Scheme 3

Substrate Scope of Carbodiimide (3 + 2) Cycloaddition.

Conditions: cyclopropane 1 (0.4 mmol), carbodiimide (0.44 equiv), tin(II) triflate (0.44 mmol), CH2Cl2 (1.3 mL). a Isolated yields. b Bis(trimethylsilyl)carbodiimide is used as the dipolarophile.