Table 1.
λmax abs [a] (nm) | λmax em [b] (nm) | η[c] | Lifetime (ns)[d]
|
δ (GM) | λmax 2PA [g] (nm) | ηδ at 820 nm (GM) | |||
---|---|---|---|---|---|---|---|---|---|
τ1 | τ2 | <τ> | |||||||
In toluene | 524 | 628 | 0.44 | 4.08 | 930[e] | 820 | 409 | ||
In THF | 524 | 658 | 0.27 | 3.77 | 520[e] | 830 | 143 | ||
In DCM | 523 | 670 | 0.09 | 2.06 | 370[e] | 830 | 30 | ||
In DMF | 527 | 674 | 0.01 | --- | --- | ---[h] | ---[h] | ||
In micelle 1 | 534 | 672 | 0.07 | 1.70 (0.54) | 4.61 (0.46) | 3.70 | 310[f] | 22 | |
In micelle 2 | 534 | 671 | 0.08 | 1.79 (0.63) | 4.36 (0.37) | 3.31 | 400[f] | 32 |
absorbance maximum;
emission maximum;
quantum yield;
the numbers in the parenthesis of τ1 and τ2 are their corresponding A1 and A2;
the maximum of the 2PA cross-sections;
the 2PA cross-sections at 820 nm;
the wavelength of the maximum 2PA cross-sections;
too weak to measure.