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. 2012 Nov;12(11):1042–1054. doi: 10.1089/ast.2012.0823

Table 1.

Different Hydrated Forms of MgSO4·nH2O (0≤n≤11) as Described in the Literature

Phase n Referencea
α-MgSO4 0 Rentzeperis and Soldatos, 1958; Fortes et al.,2007
β-MgSO4 0 Coing-Boyat, 1962; Yamaguchi and Kato, 1972; Fortes et al.,2007
γ-MgSO4 0 Rowe et al.,1967; Daimon and Kato, 1984
Kieserite 1 Hawthorne et al.,1987
Reagent monohydrateb 1 Chipera and Vaniman, 2007; Grindrod et al.,2010; Steiger et al.,2011
5/4 hydrateb 1.25 van't Hoff and Dawson, 1899; Hodenberg and Kühn, 1967
Sanderite 2 Ma et al.,2009a
2.4 hydratec 2.4 Chipera and Vaniman, 2007
2.5 hydratec 2.5 Ma et al.,2009b
Trihydrate 3 Hodenberg and Kühn, 1967; Fortes et al.,2010
Starkeyite 4 Baur, 1962, 1964a
Cranswickite 4 Peterson, 2011
Pentahydrite 5 Baur and Rolin, 1972
Hexahydrite 6 Zalkin et al.,1964
Epsomite 7 Baur, 1964b; Ferraris et al.,1973; Fortes et al.,2006
Meridianiite 11 Peterson and Wang, 2006; Peterson et al.,2007; Fortes et al.,2008
a

In case the structure is known, this reference is given.

b

The reagent monohydrate described by Chipera and Vaniman (2007) is reported to be a mixture of the 5/4 hydrate and sanderite (Grindrod et al., 2010).

c

The 2.5 hydrate described by Ma et al. (2009b) is the 2.4 hydrate reported by Chipera and Vaniman (2007) (cf. Ma et al., 2009b).