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. Author manuscript; available in PMC: 2013 Nov 12.
Published in final edited form as: Angew Chem Int Ed Engl. 2012 Oct 16;51(46):11505–11509. doi: 10.1002/anie.201206702

Scheme 5.

Scheme 5

Experimental data and trans:cis-AP selectivity obtained from oxidative cyclization of substrate 6-D-1 with a Pd(pyrox)(OAc)2 catalyst system (refer to Scheme 4 for depiction of the reaction).