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. 2012 Jul 16;18(35):10873–10885. doi: 10.1002/chem.201201023

2.

List of nonfluorescent chlorophyll catabolites (Mc-NCCs) observed in extracts of peels of ripening bananas (Musa acuminata). The common general formula B is depicted above with specification of observed covalent modifications at positions R1, R2, R3, and R4.

Compound R1 R2 R3 R4
Mc-NCC-26 CH(OH)-CH2OH OH OH H
Mc-NCC-42[a] CH(OH)-CH2OH OH OH CH3
Mc-NCC-49 CH=CH2 OH OH H
Mc-NCC-59 CH=CH2 O-Glc[b] OH CH3
Mc-NCC-61 CH=CH2 OH OH CH3
Mc-NCC-55 CH=CH2 OH daucic acid[c] CH3
Mc-NCC-58 CH=CH2 OH daucic acid[c] CH3

[a] Identified with So-NCC-2 from senescent spinach leaves[1]; [b] Glc=β-glucopyranosyl; [c] Daucic acid bound at 5′-OH or at 4′-OH.