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. Author manuscript; available in PMC: 2013 Oct 17.
Published in final edited form as: J Am Chem Soc. 2012 Oct 3;134(41):17262–17273. doi: 10.1021/ja307497h

Table 1.

Scope of the α-Quinonylation Reaction.a

graphic file with name nihms-412503-t0019.jpg

entry product yield entry product yield
1 graphic file with name nihms-412503-t0020.jpg 84% 2b graphic file with name nihms-412503-t0021.jpg 81%
3b graphic file with name nihms-412503-t0022.jpg 86% 4 graphic file with name nihms-412503-t0023.jpg 61%
5 graphic file with name nihms-412503-t0024.jpg 76% 6 graphic file with name nihms-412503-t0025.jpg 85%
7 graphic file with name nihms-412503-t0026.jpg 64% 8 graphic file with name nihms-412503-t0027.jpg 65%
9 graphic file with name nihms-412503-t0028.jpg 82% 10 graphic file with name nihms-412503-t0029.jpg 85%
a

Conditions: TASF(Et) (1.10 equiv), CH2Cl2, –78 °C.

b

THF used as solvent.