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. Author manuscript; available in PMC: 2013 Oct 17.
Published in final edited form as: J Am Chem Soc. 2012 Oct 3;134(41):17262–17273. doi: 10.1021/ja307497h

Table 2.

Scope of the γ-Quinonylation Reaction.a

graphic file with name nihms-412503-t0030.jpg

entry product and yield entry product and yield
1 graphic file with name nihms-412503-t0031.jpg 2 graphic file with name nihms-412503-t0032.jpg
3 graphic file with name nihms-412503-t0033.jpg 4 graphic file with name nihms-412503-t0034.jpg
5 graphic file with name nihms-412503-t0035.jpg 6 graphic file with name nihms-412503-t0036.jpg
7 graphic file with name nihms-412503-t0037.jpg 8 graphic file with name nihms-412503-t0038.jpg
9 graphic file with name nihms-412503-t0039.jpg 10 graphic file with name nihms-412503-t0040.jpg
a

conditions: TASF(Et) (1.1 equiv), CH2Cl2, –78 °C.

b

TBAT (1.1–1.5 equiv), CH2Cl2, 0 °C.

c

none detected by 1H NMR analysis of the unpurified reaction mixture.