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. Author manuscript; available in PMC: 2013 Nov 21.

Published in final edited form as: J Am Chem Soc. 2012 Nov 6;134(46):18912–18915. doi: 10.1021/ja3083818

a) UV-vis spectra of (F₈)Fe^III-O-Cu^II(tmpa)][B(C₆F₅)₄] (1) (), (F₈)Fe^II(NO) () generated from 1 + NO_(g) (12 µM in acetone at RT); b) EPR spectrum of the reaction products of (F₈)Fe^III-O-Cu^II(tmpa)][B(C₆F₅)₄] and NO () and; c) EPR spectrum of an authentic sample of a 1:1 F₈Fe^II(NO) and [(tmpa)Cu(NO₂)][B(C₆F₅)₄] mixture (). EPR spectra were recorded at 20 K (1 mM in MeTHF).

Inline graphic — a) UV-vis spectra of (F₈)Fe^III-O-Cu^II(tmpa)][B(C₆F₅)₄] (1) (), (F₈)Fe^II(NO) () generated from 1 + NO_(g) (12 µM in acetone at RT); b) EPR spectrum of the reaction products of (F₈)Fe^III-O-Cu^II(tmpa)][B(C₆F₅)₄] and NO () and; c) EPR spectrum of an authentic sample of a 1:1 F₈Fe^II(NO) and [(tmpa)Cu(NO₂)][B(C₆F₅)₄] mixture (). EPR spectra were recorded at 20 K (1 mM in MeTHF).