Table 1. ν(Fe-C) and ν(CO) frequencies (cm−1) of the Fe2+-CO adduct of several Ngbs.
Form 1 (no H-bond) | Form 3 (weak H-bond) | Form 2 (strong H-bond) | Reference | ||||
ν(Fe-C) | ν(CO) | ν(Fe-C) | ν(CO) | ν(Fe-C) | ν(CO) | ||
C. aceNgb* | 489 (485) | 1965 (1918) | 522 (518) | 1934 (1888) | This work | ||
D. mawNgb* | 489 (485) | 1965 (1918) | 522 (518) | 1934 (1888) | This work | ||
Mouse | 492 | 1969 | 523 | 1933 | [42] | ||
Human | 494 | 1972 | 505 | 1956 | 521 | 1932 | [43], [46] |
The frequencies obtained for the 13CO-adducts are given in parentheses.