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. Author manuscript; available in PMC: 2012 Dec 7.
Published in final edited form as: Angew Chem Int Ed Engl. 2010;49(1):34–44. doi: 10.1002/anie.200904491

Scheme 12.

Scheme 12

A racemic stereogenic-at-Ru catalyst used to promote sequence-selective polymerization; success of this strategy is due to energy differences between the two carbene diastereomers of the chiral complex.