Table 2.
# | Δh (cm−1) | ΔSD (cm−1) | τSD (ps) | τVR (ps) |
---|---|---|---|---|
1 | 1.8 | 14.0 | 30 ± 5 | 18.8 ± 0.6 |
2 | 2.2 | 16.2 | 43 ± 5 | 17.1 ± 0.6 |
3 | 1.6 | 13.4 | 30 ± 4 | 19.4 ± 0.6 |
4 | 1.55 | 13.3 | 35 ± 6 | 19.1 ± 0.4 |
5 | 1.1 | 14.4 | 42 ± 11 | 18.6 ± 0.4 |
6 | 1.9 | 14.9 | 50 ± 10 | 18.6 ± 0.4 |
avg. | 1.7 | 14.4 | 37 ± 5 | 18.6 ± 0.8 |
Δh – Homogeneous linewidth (FWHM) found by simultaneous analysis of initial CLS and absorption linewidth
ΔSD –Inhomogeneous spectrally diffusing linewidth (FWHM) found by simultaneous analysis of initial CLS and absorption linewidth
τVR – Vibrational lifetime measured by heterodyne detected transient grating spectroscopy