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. Author manuscript; available in PMC: 2013 Nov 8.
Published in final edited form as: J Phys Chem C Nanomater Interfaces. 2012 Nov 8;116(44):23428–23440. doi: 10.1021/jp307677b

Table 2.

Parameters from linear IR spectroscopy describing the mixed monolayers synthesized for study by ultrafast infrared spectroscopy.

# Δh (cm−1) ΔSD (cm−1) τSD (ps) τVR (ps)
1 1.8 14.0 30 ± 5 18.8 ± 0.6
2 2.2 16.2 43 ± 5 17.1 ± 0.6
3 1.6 13.4 30 ± 4 19.4 ± 0.6
4 1.55 13.3 35 ± 6 19.1 ± 0.4
5 1.1 14.4 42 ± 11 18.6 ± 0.4
6 1.9 14.9 50 ± 10 18.6 ± 0.4
avg. 1.7 14.4 37 ± 5 18.6 ± 0.8

Δh – Homogeneous linewidth (FWHM) found by simultaneous analysis of initial CLS and absorption linewidth

ΔSD –Inhomogeneous spectrally diffusing linewidth (FWHM) found by simultaneous analysis of initial CLS and absorption linewidth

τVR – Vibrational lifetime measured by heterodyne detected transient grating spectroscopy