Table 4.
entry | allylsilane product | yield (%)b | Z:E c | erd |
---|---|---|---|---|
1e | 85 | 78:12 | 95:5 | |
2 | 91 | 95:5 | 98:2 | |
3 | 95 | >98:2 | 95:5 | |
4 | 91 | >98:2 | 97:3 | |
5 | 88 | >98:2 | 94.5:5.5 | |
6 | 92 | 95:5 | 98:2 | |
7 | 95 | <2:>98 | 96:4 | |
8 | 98 | 96:4 | 96:4 |
See Table 3.
See Table 3.
See Table 3.
See Table 3.
Product mixture contained 15–20% of the isomerized α,β-unsaturated ketone. See the SI for details.