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. Author manuscript; available in PMC: 2013 Nov 26.
Published in final edited form as: Organometallics. 2012 Sep 19;31(22):7823–7826. doi: 10.1021/om300790t

Table 4.

Additions to β-Substituted Cyclic Dienonesa

graphic file with name nihms-409246-t0013.jpg

entry allylsilane product yield (%)b Z:E c erd
1e graphic file with name nihms-409246-t0014.jpg 85 78:12 95:5
2 graphic file with name nihms-409246-t0015.jpg 91 95:5 98:2
3 95 >98:2 95:5
4 91 >98:2 97:3
5 88 >98:2 94.5:5.5
6 graphic file with name nihms-409246-t0016.jpg 92 95:5 98:2
7 graphic file with name nihms-409246-t0017.jpg 95 <2:>98 96:4
8 graphic file with name nihms-409246-t0018.jpg 98 96:4 96:4
a

See Table 3.

b

See Table 3.

c

See Table 3.

d

See Table 3.

e

Product mixture contained 15–20% of the isomerized α,β-unsaturated ketone. See the SI for details.