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. Author manuscript; available in PMC: 2014 Jan 15.
Published in final edited form as: Coord Chem Rev. 2013 Jan 15;257(2):528–540. doi: 10.1016/j.ccr.2012.06.003

Table 1.

Common chemical oxidants used to general metal-salen phenoxyl radicals [36].

Oxidant Solvent E°′ (V) (vs Fc/Fc+)
[NO]+ CH2Cl2 1.00
Ce(IV) H2O 0.88
Th+ MeCN 0.86
[N(C6H5Br-4)3]+ CH2Cl2 0.70
Ag+ CH2Cl2 0.65
[Fe(η-C5H4COMe)2]+ CH2Cl2 0.49
[Fe(η-C5H4COMe)Cp]+ CH2Cl2 0.27