Table 1. Concentrations (ng/g Dust) of Flame Retardants and Legacy Organohalogens in California House Dust from 16 Homes Sampled in 2006 and 2011.
2006
samples (round 1; n = 16) |
2011
samples (round 2; n = 16) |
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---|---|---|---|---|---|---|---|---|---|---|
chemical name | abbreviationa | LOQb | % > LOQ | min. | median | max. | % > LOQ | min. | median | max. |
Polybrominated Diphenyl Ethers (PBDEs) | ||||||||||
2,4,4′-tribromodiphenyl ether | BDE 28 | 2 | 100 | 5 | 26 | 270 | 100 | 3 | 14 | 310 |
2,2′,4,4′-tetrabromodiphenyl ether | BDE 47 | 2 | 100 | 270 | 2300 | 23 000 | 100 | 140 | 1,000 | 17 000 |
2,3′,4,4′-tetrabromodiphenyl ether | BDE 66 | 2 | 100 | 8 | 64 | 520 | 100 | 4 | 23 | 1800 |
2,2′,3,4,4′-pentabromodiphenyl ether | BDE 85 | 3 | 100 | 13 | 110 | 1300 | 100 | 9 | 66 | 6000 |
2,2′,4,4′,5-pentabromodiphenyl ether | BDE 99 | 2 | 100 | 280 | 2200 | 24 000 | 100 | 190 | 1100 | 25 000 |
2,2′,4,4′,6-pentabromodiphenyl ether | BDE 100 | 2 | 100 | 56 | 520 | 4900 | 100 | 37 | 240 | 11 000 |
2,2′,4,4′,5,5′-hexabromodiphenyl ether | BDE 153 | 3 | 100 | 2 | 250 | 2400 | 100 | 21 | 150 | 7800 |
2,2′,4,4′,5,6′-hexabromodiphenyl ether | BDE 154 | 3 | 100 | 22 | 240 | 1800 | 100 | 17 | 110 | 6700 |
2,2′,3,4,4′,5′,6-heptabromodiphenyl ether | BDE 183 | 4 | 100 | 9 | 28 | 770 | 100 | 3 | 18 | 920 |
2,2′,3,3′,4,4′,5,6′-octabromodiphenyl ether | BDE 196 | 4 | 88 | <4 | 7.5 | 240 | 56 | <4 | 4 | 180 |
2,2′,3,3′,4,4′,6,6′-octabromodiphenyl ether | BDE 197 | 4 | 81 | <4 | 9 | 530 | 56 | <4 | 4 | 230 |
2,2′,3,4,4′,5,5′,6-octabromodiphenyl ether | BDE 203 | 4 | 81 | <4 | 5 | 130 | 50 | <4 | 2 | 110 |
decabromodiphenyl ether | BDE 209 | 10 | 100 | 580 | 1400 | 15 000 | 100 | 110 | 1200 | 8500 |
Firemaster 550 | ||||||||||
2-ethylhexyl-2,3,4,5-tetrabromobenzoate | EH-TBB (or TBB) | 2 | 100 | 4 | 48 | 740 | 100 | 45 | 100 | 5900 |
bis(2-ethylhexyl)-3,4,5,6-tetrabromophthalate | BEH-TEBP (or TBPH) | 2 | 100 | 36 | 140 | 1900 | 94 | <2 | 260 | 3800 |
triphenyl phosphate | TPHP | 20 | 100 | 580 | 3000 | 14 000 | 100 | 790 | 2800 | 36 000 |
Tetrabromobisphenol A | ||||||||||
tetrabromobisphenol A | TBBPA | 10 | 94 | <10 | 260 | 3400 | 100 | 22 | 200 | 2000 |
Hexabromocyclododecane | ||||||||||
α-hexabromocyclododecane | α-HBCYD (or α-HBCD) | 5 | 100 | 31 | 62 | 710 | 100 | 17 | 62 | 910 |
β-hexabromocyclododecane | β-HBCYD (or β-HBCD) | 5 | 100 | 8 | 18 | 330 | 100 | 7 | 16 | 230 |
γ-hexabromocyclododecane | γ-HBCYD (or γ-HBCD) | 5 | 100 | 29 | 94 | 6700 | 100 | 13 | 73 | 790 |
hexabromocyclododecane | Σ HBCYD (or HBCD) | 5 | 100 | 82 | 190 | 6800 | 100 | 39 | 160 | 1800 |
Other Brominated Flame Retardants (BFRs) | ||||||||||
hexabromobenzene | HBB | 2 | 50 | <2 | 1 | 8 | 31 | <2 | <2 | 13 |
hexachlorocyclopentadienyl-dibromocyclooctane | DBHCTD (or HCDBCO) | 5 | 6 | <5 | <5 | 9 | 25 | <5 | <5 | 72 |
1,2-bis(2,4,6-tribromophenoxy)ethane | BTBPE | 2 | 100 | 7 | 30 | 220 | 100 | 3 | 12 | 130 |
decabromodiphenylethane | DBDPE | 10 | 94 | <10 | 51 | 430 | 100 | 18 | 140 | 2800 |
tetrabromobisphenol A - bis(2,3-dibromopropylether) | TBBPA-BDBPE (or TBBPA-dbpe) | 10 | 75 | <10 | 22 | 180 | 50 | <10 | 7 | 560 |
α-1,2-dibromo-4-(1,2-dibromoethyl)cyclohexane | α-DBE-DBCH (or α-TBECH) | 2 | 6 | <2 | <2 | 13 | 19 | <2 | <2 | 25 |
β-1,2-dibromo-4-(1,2-dibromoethyl)cyclohexane | β-DBE-DBCH (or β-TBECH) | 2 | 6 | <2 | <2 | 11 | 12 | <2 | <2 | 16 |
γ-1,2-dibromo-4-(1,2-dibromoethyl)cyclohexane | γ-DBE-DBCH (or γ-TBECH) | 2 | 0 | – | – | – | 6 | <2 | <2 | 3 |
δ-1,2-dibromo-4-(1,2-dibromoethyl)cyclohexane | δ-DBE-DBCH (or δ-TBECH) | 2 | 0 | – | – | – | 0 | – | – | – |
2,4,6-tribromophenyl allyl ether | TBP-AE (or ATE) | 2 | 0 | – | – | – | 0 | – | – | – |
2-bromoallyl-2,4,6-tribromophenyl ether | TBP-BAE (or BATE) | 2 | 0 | – | – | – | 0 | – | – | – |
2,4,6-tribromophenyl 2,3-dibromopropyl ether | TBP-DBPE (or DPTE) | 2 | 6 | <2 | <2 | 2 | 6 | <2 | <2 | 11 |
α-1,2,5,6-tetrabromocyclooctane | α-TBCO | 2 | 6 | <2 | <2 | 2 | 0 | – | – | – |
β-1,2,5,6-tetrabromocyclooctane | β-TBCO | 2 | 0 | – | – | – | 0 | – | – | – |
octabromo-1,3,3-trimethyl-1-phenylindane | OBTMPI (or OBIND) | 5 | 44 | <5 | <5 | 130 | 25 | <5 | <5 | 62 |
Halogenated Organophosphate Flame Retardants (OPFRs) | ||||||||||
tris(2-chloroethyl)-phosphate | TCEP | 20 | 100 | 610 | 5100 | 160 000 | 100 | 330 | 2700 | 110 000 |
tris(1-chloro-2-propyl)-phosphate | TCIPP (or TCPP) | 20 | 100 | 340 | 2100 | 120 000 | 100 | 490 | 2200 | 140 000 |
tris(1,3-dichloro-isopropyl)-phosphate | TDCIPP (or TDCPP) | 20 | 100 | 730 | 2800 | 24 000 | 100 | 920 | 2100 | 44 000 |
tris(2,3-dibromopropyl) phosphate | TDBPP | 20 | 62 | <20 | 35 | 8900 | 38 | <20 | <20 | 310 |
Nonhalogenated Organophosphate Flame Retardants (OPFRs) | ||||||||||
triethyl-phosphate | TEP | 20 | 56 | <20 | 28 | 410 | 31 | <20 | <20 | 250 |
tri-n-propyl-phosphate | TnPP (or TPP) | 20 | 0 | – | – | – | 0 | – | – | – |
tri-iso-butyl-phosphate | TIBP (or TiBP) | 80 | 56 | <80 | 84 | 180 | 19 | <80 | <80 | 120 |
tri-n-butyl-phosphate | TNBP (or TnBP) | 80 | 50 | <80 | 32 | 1800 | 38 | <80 | <80 | 1800 |
tri-(2-butoxyethyl)-phosphate | TBOEP (or TBEP) | 300 | 100 | 2300 | 12 000 | 68 000 | 100 | 790 | 11 000 | 170 000 |
tri-(2-ethylhexyl)-phosphate | TEHP | 200 | 19 | <200 | <200 | 3700 | 12 | <200 | <200 | 340 |
ethylhexyl diphenyl phosphate | EHDPP | 100 | 100 | 180 | 610 | 3000 | 100 | 140 | 560 | 1500 |
tricresyl phosphate | TMPP (or TCP) | 20 | 100 | 330 | 1000 | 4400 | 100 | 180 | 680 | 10 000 |
Dechlorane Plus (DP) | ||||||||||
syn-Dechlorane Plus | syn-DP | 2 | 81 | <2 | 3 | 22 | 44 | <2 | <2 | 7 |
anti-Dechlorane Plus | anti-DP | 2 | 100 | 3 | 7.5 | 35 | 75 | <2 | 3 | 8 |
Dechlorane Plus | Σ DP | 2 | 100 | 3 | 10 | 47 | 75 | <2 | 4.5 | 15 |
Legacy Compounds | ||||||||||
2,2′,4,4′,5,5′-hexachlorobiphenyl | CB 153 | 5 | 100 | 6 | 18 | 200 | 81 | <5 | 9.5 | 130 |
2,2′,3,4,4′,5,5′-heptachlorobiphenyl | CB 180 | 5 | 94 | <5 | 16 | 74 | 75 | <5 | 8.5 | 90 |
3,3′,5,5′-tetrabromo biphenyl | BB 80 | 3 | 0 | – | – | – | 6 | <3 | <3 | 6 |
2,2′,4,5′,6-pentabromo biphenyl | BB 103 | 3 | 0 | – | – | – | 6 | <3 | <3 | 3 |
2,2′,4,4′,5,5′-hexabromo biphenyl | BB 153 | 3 | 56 | <3 | 4.5 | 160 | 44 | <3 | <3 | 47 |
2,2′,3,4,4′,5,5′-heptabromo biphenyl | BB 180 | 5 | 0 | – | – | – | 0 | – | – | – |
decabromo biphenyl | BB 209 | 10 | 0 | – | – | – | 0 | – | – | – |
cis-chlordane | CC | 5 | 94 | <5 | 26 | 250 | 94 | <5 | 17 | 180 |
trans-chlordane | TC | 5 | 94 | <5 | 34 | 280 | 100 | 5 | 22 | 220 |
trans-nonachlor | TN | 5 | 94 | <5 | 19 | 130 | 88 | <5 | 11 | 140 |
1,1,1-trichloro-2,2-di(4-chlorophenyl)ethane | p,p′-DDT | 10 | 100 | 44 | 530 | 4100 | 100 | 50 | 160 | 1500 |
1,1-bis-(4-chlorophenyl)-2,2-dichloroethene | p,p′-DDE | 10 | 94 | <10 | 74 | 430 | 88 | <10 | 40 | 170 |
1,1-dichloro-2-(2-chlorophenyl)-2-(4-chlorophenyl)ethane | p,p′-DDD | 10 | 88 | <10 | 36 | 240 | 75 | <10 | 14 | 64 |
Compounds were named following the newly proposed nomenclature presented by Bergman et al,61 with the older name give in parentheses.
LOQ, limit of quantification; – indicates insufficient number of detects to calculate summary statistics.