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. Author manuscript; available in PMC: 2012 Dec 19.
Published in final edited form as: European J Org Chem. 2009 Oct 8;2009(32):5487–5500. doi: 10.1002/ejoc.200900560

Table 3.

CM of 4 with type I, II, and III olefins. All entries reported used with cat-C catalyst.

Entry CM
partner
Product % Yield E/Z Type
1 graphic file with name nihms425058t11.jpg graphic file with name nihms425058t12.jpg 86 >99:1 I
2 graphic file with name nihms425058t13.jpg graphic file with name nihms425058t14.jpg 87 >99:1 I
3 graphic file with name nihms425058t15.jpg graphic file with name nihms425058t16.jpg 69 >99:1 I
4 graphic file with name nihms425058t17.jpg graphic file with name nihms425058t18.jpg 80 2:1 I
5 graphic file with name nihms425058t19.jpg graphic file with name nihms425058t20.jpg 78 8:1 II
6 graphic file with name nihms425058t21.jpg graphic file with name nihms425058t22.jpg 60 5:1 II
7 graphic file with name nihms425058t23.jpg graphic file with name nihms425058t24.jpg 78 >99:1 II
8 graphic file with name nihms425058t25.jpg graphic file with name nihms425058t26.jpg 72 >99:1 II
9 graphic file with name nihms425058t27.jpg graphic file with name nihms425058t28.jpg <5[a] n/a III
10 graphic file with name nihms425058t29.jpg graphic file with name nihms425058t30.jpg <5[a] n/a III
11 graphic file with name nihms425058t31.jpg <5[b] n/a III
12 graphic file with name nihms425058t32.jpg graphic file with name nihms425058t33.jpg n.r.[b] n/a III
[a]

Used 4.0 equiv. of CM partner.

[b]

Reaction attempted neat.