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. Author manuscript; available in PMC: 2013 Mar 29.
Published in final edited form as: J Chem Theory Comput. 2012 Mar 29;8(10):3574–3585. doi: 10.1021/ct2009329

Figure 2.

Figure 2

A schematic description of the relationship between the free-energy difference between the reactant and product states (ΔG0), and the activation free energy (Δg‡). This figure illustrates how shifting εp by ΔΔG0 (which changes εp to εp′ and ΔG0 to ΔG0 + ΔΔG0) changes Δg‡ by a proportional amount.