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. Author manuscript; available in PMC: 2014 Jan 16.
Published in final edited form as: J Am Chem Soc. 2013 Jan 8;135(2):751–762. doi: 10.1021/ja309176h

Table 4.

Stoichiometric Reactivity of Allylnickel IIA.a

graphic file with name nihms432185u4.jpg
entry conditionsb Yield
P (%)		 Yield
B (%)		 Yield
E (%)
PhI Mn0 Et3SiCl
1 0 0 0 0 0 0
2 100 0 0 12 0 0
3 100 0 110 7 0 0
4 100 110 200 71 0 0
5 1.0 110 200 28 0 0
6 100 0d 0 26 0 0
7 catalytic reaction with Ni(acac)2 and L10 99e 0 13e
8 Catalytic reaction with Ni(acac)2, L10, and pyr 69e 0 14e
a

Nickel complexes were generated in situ at a concentration of 2.5 mM in DMA and reacted with the noted reagents. Analysis at 5 minutes (GC, corrected) provided the stated yields. For stoichiometric reactions (1–6), the yield is calculated from starting nickel complex IIA.

b

Equivalents with respect to [Ni].

c

Mn0 powder was pre-stirred with Et3SiCl.

d

TDAE = tetrakis(dimethylamino)ethylene.

e

Yield calculated from the amount of enone added to catalytic reactions (0.5 mmol).