Table 1.
1H | 13C | |||
---|---|---|---|---|
# | 1 | 2 | 1 | 2 |
2 | 164.1, C | 164.6, C | ||
3 | 126.9, C | 128.6, C | ||
4 | 7.52, br s | 7.92, br s | 141.4, CH | 143.1, CH |
4a | 116.7, C | 117.0, C | ||
5 | 6.76, br s | 7.02, br s | 106.1, CH | 105.3, CH |
6 | 152.0, C | 156.5, C | ||
6a | 117.6, C | 120.4, C | ||
7 | 157.2, C | 160.2, C | ||
8 | 6.97, d (8.4) | 7.14, d (7.8) | 108.0, CH | 112.1, CH |
9 | 7.49, t (8.4) | 7.59, t (7.8) | 128.5, CH | 131.5, CH |
10 | 8.14, d (8.4) | 7.86, d (7.8) | 115.8, CH | 116.2, CH |
10a | 126.4, C | 128.9, C | ||
10b | 143.6, C | 146.2, C | ||
3-Me | 2.26, s | 2.14, s | 17.1, CH3 | 19.9, CH3 |
6-OMe | 3.87, s | 59.4, CH3 | ||
7-OMe | 4.10, s | 3.88, s | 56.9, CH3 | 59.4, CH3 |
δ (ppm) 600 MHz; multiplicities; J values (Hz) in parentheses; 1 in CDCl3; 2 in DMSO-d6.
δ (ppm) 150 MHz; 1 in 50% CDCl3/CD3OD; 2, in DMSO-d6, chemical shifts from gHSQC and gHMBC.