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. Author manuscript; available in PMC: 2013 Dec 6.
Published in final edited form as: J Phys Chem Lett. 2012 Dec 6;3(23):3538–3544. doi: 10.1021/jz301670s

Figure 4.

Figure 4

These panels are as in Fig. 3 except they show the effects of mass substitution in 10 reactive trajectories in the light (panels a and b) and the heavy enzyme (panels c and d) in leaving group interactions. The results from 5 different trajectories are depicted in each panel. As in the previous figure, the trajectories are aligned so that 200 fs is the transition point. Again, as in the previous figure, mass substitution causes a significant shift in timing of the maximum effect of this stabilizing promoting vibration.