Table 1.
Properties of the polymers
λ ab,
a nm
|
λ em,
b nm
|
CMC mg/mL | Diameter, e (nm) | 19F T1, h (ms) | 19F T2, h (ms) | 19F T1, i (ms) | 19F T2, i (ms) | |||
---|---|---|---|---|---|---|---|---|---|---|
Soln, c | Aggr, d | Soln (η) | Aggr (η) | |||||||
P1 | 412 | 405 | 521 (0.013) | 530 (2.0) | 0.033 | ----f | ||||
P2 | 408 | 405 | 518 (0.011) | 535 (2.1) | 0.032 | 6.9 | ||||
P3 | 418 | 414 | 528 (0.013) | 538 (8.7) | 0.014 | 8.6 | ||||
P4 | 420 | 415 | 530 (0.013) | 540 (10.1) | 0.011 | 8.0 | ||||
P5 | 420 | 416 | 533 (0.010) | 540 (10.4) | 0.006 | 8.1 | ||||
PF1 | 422 | 417 | 520 (0.010) | 531 (3.9) | 0.041 | 22 | 274 | 65 | ||
PF2 | 419 | 415 | 520 (0.016) | 524 (16.5) | 0.034 | 26 | 237 | 28 | 215 | 33 |
PF3 | 418 | 415 | 520 (0.012) | 525 (19.7) | 0.034 | 21 | 276 | 36 | 260 | 42 |
PF4 | 416 | 411 | 520 (0.017) | 516 (38.3) | 0.033 | 21 | 244 | 11 | ||
PF5 | 411 | 410 | 521 (0.003) | 518 (40.7) | 0.034 | ----g |
Absorption maximum.
Emission maximum (with quantum yield (η, %) given in the parentheses); excitation wavelength: 425 nm.
Solutions (in DMSO).
Aggregates (in 2% DMSO aqueous solutions).
by DLS.
no reliable data.
not measured because of the poor solubility.
in 2% DMSO aqueous solutions with polymer concentrations of 10 mg/mL.
in 10 mM HEPES buffers (pH 7.2) with polymer concentrations of 10 mg/mL.