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. Author manuscript; available in PMC: 2013 Nov 26.
Published in final edited form as: Angew Chem Int Ed Engl. 2012 Oct 18;51(48):12016–12019. doi: 10.1002/anie.201205905

Table 1.

Secondary structural elements from CD spectra [%].

Sample α-helix β-sheet β-turn Random coil
No treatment
Free ChT[a] 10.0 34.0 20.0 36.0
Free ChT[b] 11.3 33.3 18.9 34.4
ChT and PEG-PMA/MNP[c] 12.5 33.3 19.4 35.3
ChT-PEG-PMA/MNP[d] 11.6 33.4 19.1 34.9
RF: 337 kHz, 21 kAm−1 2.5 minx3
Free ChT[b] 11.1 33.5 19.1 36.3
ChT and PEG-PMA/MNP[c] 11.4 34.7 22.0 34.9
ChT-PEG-PMA/MNP[d] 26.8 21.7 18.5 33.6
Heating: 60°C, 10 min
Free ChT[b] 3.4 40.4 18.2 41.4
ChT and PEG-PMA/MNP[c] 2 47.5 15.7 40.3
ChT-PEG-PMA/MNP[d] 12.1 29.8 13.8 42.6
[a]

Theoretical values.

[b]

Experimental values.

[c]

Non-conjugated mixture.

[d]

Covalently conjugated. ChT/PEG-PMA/MNP-3 was utilized.