Table 1.
Sample | α-helix | β-sheet | β-turn | Random coil |
---|---|---|---|---|
No treatment | ||||
Free ChT[a] | 10.0 | 34.0 | 20.0 | 36.0 |
Free ChT[b] | 11.3 | 33.3 | 18.9 | 34.4 |
ChT and PEG-PMA/MNP[c] | 12.5 | 33.3 | 19.4 | 35.3 |
ChT-PEG-PMA/MNP[d] | 11.6 | 33.4 | 19.1 | 34.9 |
RF: 337 kHz, 21 kAm−1 2.5 minx3 | ||||
Free ChT[b] | 11.1 | 33.5 | 19.1 | 36.3 |
ChT and PEG-PMA/MNP[c] | 11.4 | 34.7 | 22.0 | 34.9 |
ChT-PEG-PMA/MNP[d] | 26.8 | 21.7 | 18.5 | 33.6 |
Heating: 60°C, 10 min | ||||
Free ChT[b] | 3.4 | 40.4 | 18.2 | 41.4 |
ChT and PEG-PMA/MNP[c] | 2 | 47.5 | 15.7 | 40.3 |
ChT-PEG-PMA/MNP[d] | 12.1 | 29.8 | 13.8 | 42.6 |
Theoretical values.
Experimental values.
Non-conjugated mixture.
Covalently conjugated. ChT/PEG-PMA/MNP-3 was utilized.