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. Author manuscript; available in PMC: 2014 Feb 19.
Published in final edited form as: Acc Chem Res. 2012 Nov 16;46(2):506–518. doi: 10.1021/ar300216r

Table 7.

Desymmetrization of meso-Secondary Allylic and Homoallylic Alcohols

graphic file with name nihms421921u8.jpg
ligand oxidant product T (°C) time (h) d.r. yield (%) ee(%)
8a TBHP graphic file with name nihms421921t70.jpg 0 10 94:6 52 95
8a TBHP graphic file with name nihms421921t71.jpg 0 12 95:5 60 95
8a TBHP graphic file with name nihms421921t72.jpg −10 96 99:1 62 95
8b TBHP graphic file with name nihms421921t73.jpg −10 96 87:13 73 97
8e TBHP graphic file with name nihms421921t74.jpg 0 24 98:2 52 95
8e CHP graphic file with name nihms421921t75.jpg 0 120 92:8 51 97
8e CHP graphic file with name nihms421921t76.jpg 0 96 97:3 69 97
8e CHP graphic file with name nihms421921t77.jpg 0 96 60:40 40 17, 23