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. Author manuscript; available in PMC: 2014 Feb 19.
Published in final edited form as: Acc Chem Res. 2012 Nov 16;46(2):506–518. doi: 10.1021/ar300216r

Table 8.

Mo-BHA Catalyzed Asymmetric Epoxidation of Olefins

graphic file with name nihms421921u9.jpg
ligand epoxide oxidant time (h) yield (%) ee (%)
8g graphic file with name nihms421921t78.jpg THP 18 98 95
8f graphic file with name nihms421921t79.jpg THP 20 94 92
8g graphic file with name nihms421921t80.jpg THP 20 60 90
8d graphic file with name nihms421921t81.jpg TBHP 20 92 96
8d graphic file with name nihms421921t82.jpg CHP 22 77 64
8d graphic file with name nihms421921t83.jpg CHP 40 95 85
8d graphic file with name nihms421921t84.jpg CHP 36 84 82
8d graphic file with name nihms421921t85.jpg CHP 40 95 85
8d graphic file with name nihms421921t86.jpg CHP 40 92 50
8d graphic file with name nihms421921t87.jpg TBHP 36 44 62
8d graphic file with name nihms421921t88.jpg CHP 36 92 85
8d graphic file with name nihms421921t89.jpg CHP 46 94 66 (de)
8h graphic file with name nihms421921t90.jpg CHP 42 82 76
8d graphic file with name nihms421921t91.jpg TBHP 17 13 43