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. 2013 Jan 14;288(8):5357–5363. doi: 10.1074/jbc.C112.421768

TABLE 1.

Theoretical and observed masses of the parent ion containing the phenylhydrazine-derivatized LTQ cross-link

Mass (theoretical) Mass (observed) Parent iona,b,c
1739.2 1738.7 (α+β+PH+3H)3+
1304.7 1304.6 (α+β+PH+4H)4+
1043.9 1044.2 (α+β+PH+5H)5+

a α = peptides 670–690, containing Tyr-689 of the LTQ cofactor, minus 2H+.

b β = peptides 648–669, containing Lys-653 of the LTQ cofactor, minus H+.

c PH = phenyl–N=N–.