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. Author manuscript; available in PMC: 2014 Mar 21.
Published in final edited form as: Analyst. 2013 Mar 21;138(6):1665–1673. doi: 10.1039/c2an36478f

Table 2.

Amount of spectra with suppressed Amide I bands in TERS and SERS studies of native insulin and insulin fibrils.

Method Metal of
nano-
particles
Excitation
wavelength,
nm
Native
Insulin,
average,
%
Insulin
fibrils,
average,
%
TERS silver 532 53±4 58±26
SERS silver 532 - 63±9
SERS gold 785 40±3.5 35±4.5