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. Author manuscript; available in PMC: 2014 Jan 1.
Published in final edited form as: Coord Chem Rev. 2012 Jun 1;257(1):187–195. doi: 10.1016/j.ccr.2012.05.031

Table 1.

Activation parameters for electron transfer from Fc* and Me8Fc to [CuII2(N3)]4+ and [CuII2(N3)(O22−)]2+ in acetone.

Activation parameter [CuII2 (N3)]4+ [CuII2(N3)(O22−)]2+
Fc* Me8Fc Fc* Me8Fc
ΔH≠, kcal mol−1 8.7 ± 8.5 ± 0.2 9.6 ± 0.3 10.3 ± 0.3
ΔS≠, cal K−1 0 ± 2 −3 ± 2 −3 ± 2 −1 ± 2