Table 3.
Class | Compound | log kcat (M−1 s−1) | Reference |
---|---|---|---|
Mn porphyrins | MnMx-2-PyP-Calbio | <6.5.a | [60] |
MnTM-2-PyP | 7.79 | [12] | |
MnTE-2-PyP | 7.76 | [12] | |
MnTnHex-2-PyP | 7.48 | [12] | |
MnTTEG-2-PyP | 8.11 | [13] | |
MnBr8TSPP | 5.56 | [11] | |
Mn salens | EUK-8 | 5.78 | [20] |
EUK-134 | 5.78 | [19] | |
EUK-189 | 5.78 | [19] | |
Mn cyclic polyamines | M40403 | 7.08,6.55 | [48,67] |
M40404 | Inactive | [48] | |
Control | Mn2+ | 6.1 – 7.7 | [20] |
This is not a single compound, but a mixture of several differently N-methylated Mn porphyrins that are present in a mixture in approximately same amounts(see text). Thus, the log kcat is likely lower than 6.5 M−1 s−1 based on the data for tri- (log kcat = 6.63) and di-methylated species (log kcat = 6.52) [60].