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. Author manuscript; available in PMC: 2013 Mar 8.
Published in final edited form as: Free Radic Biol Med. 2009 Apr 21;47(3):250–260. doi: 10.1016/j.freeradbiomed.2009.04.018

Table 3.

Superoxide dismutase activity (log kcat) of the Mn compounds studied

Class Compound log kcat (M−1 s−1) Reference
Mn porphyrins MnMx-2-PyP-Calbio <6.5.a [60]
MnTM-2-PyP 7.79 [12]
MnTE-2-PyP 7.76 [12]
MnTnHex-2-PyP 7.48 [12]
MnTTEG-2-PyP 8.11 [13]
MnBr8TSPP 5.56 [11]
Mn salens EUK-8 5.78 [20]
EUK-134 5.78 [19]
EUK-189 5.78 [19]
Mn cyclic polyamines M40403 7.08,6.55 [48,67]
M40404 Inactive [48]
Control Mn2+ 6.1 – 7.7 [20]
a

This is not a single compound, but a mixture of several differently N-methylated Mn porphyrins that are present in a mixture in approximately same amounts(see text). Thus, the log kcat is likely lower than 6.5 M−1 s−1 based on the data for tri- (log kcat = 6.63) and di-methylated species (log kcat = 6.52) [60].