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. 2013 Feb 15;9:342–391. doi: 10.3762/bjoc.9.39

Figure 21.

Figure 21

(a) View of the dinuclear unit in the crystal structure of [Fe2(Hsaltrz)5(NCS)4]·4MeOH. (b) Temperature dependence of χMT versus T revealing a steep spin transition from [HS–HS] to [LS–LS] pairs. The tubes show the color change from yellow at room temperature to burgundy at liquid nitrogen temperature. The DSC response, shown in the inset, confirms that a first-order phase transition takes place on cooling and warming [235].