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(left) View of the 2D layered structure of [Fe(btr)2(NCS)2]·H2O (at 293 K). The water molecules (in violet) are located between the layers and H-bonded to triazole ligands [325]. (right) χMT versus T showing a square-shaped hysteresis loop on cooling. The structural distortion parameter Σ remains the same in the HS and LS states revealing that the local symmetry is not modified by the spin state change [330].
