. 2013 Jan 24;52(7):1236–1248. doi: 10.1021/bi301417z

Table 2. Summary of the Peak Assignments for Backbone Vibrational Modes within the Amide I′ Band (1710–1600 cm^–1) As Determined by the Synchronous and Asynchronous Plots.

		Hscen1^a peak position (cm^–1)		Hscen2^a peak position (cm^–1)		Hscen3^a peak position (cm^–1)
peak assignment	average peak position (cm^–1)	5–35 °C	40–95 °C	5–35 °C	40–95 °C	5–35 °C	40–60 °C	60–90 °C
CaBS loop^b	1682.8	1686.0	1687.5	1680.0	1683.7	1684.3	1682.4	1675.7
loops	1668.1	1668.8	1666.0	1666.7	1672.5	1671.4	1668.6	1662.8
π-helix	1653.1	1653.7	1652.0	1653.4	1653.7	1654.2	1654.8	1649.9
α-helix	1643.9	1642.5	1642.0	1643.4	1646.2	1641.4	1645.6	1646.1
β-sheet	1631.2	1635.0	1626.0	1636.7	1638.7	1626.3	1627.2	1628.7

Underlined peak positions represent the greatest intensity change (i.e., the level of perturbation or flexibility) for the auto peaks within the synchronous plot.

The calcium binding site (CaBS) loop would ordinarily be assigned as a β-turn, but for relevant structural discussions related to the well-known EF-hand motif, we have used the nomenclature associated with these calcium binding proteins.

Table 2. Summary of the Peak Assignments for Backbone Vibrational Modes within the Amide I′ Band (1710–1600 cm–1) As Determined by the Synchronous and Asynchronous Plots.

Table 2. Summary of the Peak Assignments for Backbone Vibrational Modes within the Amide I′ Band (1710–1600 cm^–1) As Determined by the Synchronous and Asynchronous Plots.