Table 1.

Retention time and mass spectral data of polyphenolic compounds detected in ethanolic extract of black chokeberry fruits.

Nonanthocyanin polyphenols
Peak no.	Rt (min)	Mass spectral data		Peak assignment
		Deprotonated molecule [M–H]− (m/z)	Fragment ions (m/z)
1	32.9	352.90	190.93 [M-H-Caffeoyl]	Chlorogenic acid (5-O-caffeoyl quinic acid)
3	61.9	608.87	—	Rutin*  (quercetin-3-O-glucorhamnoside)
4	63.2	462.86	—	Hyperoside (quercetin-3-O-galactoside)
5	87.9	300.86	—	Quercetin
Anthocyanins
Peak no.	Rt (min)	Mass spectral data		Peak assignment
		Molecular ion [M]+ (m/z)	Fragment ions (m/z)
2	39.3	449.21	287.13 [M-Glucose]	Kuromanin (cyanidin-3-O-glucoside)

*Rutin coeluted with a compound (462.86 m/z), possibly another quercetin glycoside.

Rt: retention time.