Table 3. Crystal-structure data for takovite- and hydrotalcite-like phases.
In all cases x
O2 =
and Z = 3; other details are given in the text.
| Ni(OH)2H2O | [Ni0.667Al0.333(OH)2](CO3)0.1670.5H2O | Mg(OH)2H2O | [Mg0.667Al0.333(OH)2](CO3)0.1670.5H2O | |
|---|---|---|---|---|
|
|
|
|
|
| a () | 3.098 | 3.020 | 3.133 | 3.040 |
| c () | 24.480 | 22.785 | 25.539 | 22.705 |
| V cell (3) | 203.47 | 179.97 | 217.10 | 181.72 |
| z O1 | 0.3747 | 0.3766 | 0.3739 | 0.3777 |
| z H1 | 0.4155 | 0.4205 | 0.4131 | 0.4217 |
| V oct (3) | 11.214 | 10.389 | 11.743 | 10.750 |
| d(MO) () | 2.055 | 2.003 | 2.085 | 2.024 |
| h(oct) () | 2.024 | 1.973 | 2.074 | 2.013 |
| h(inter) () | 6.136 | 5.622 | 6.439 | 5.555 |
| M r (gmol1) | 110.72 | 101.15 | 76.335 | 78.221 |
| D c (gcm3) | 2.711 | 2.800 | 1.752 | 2.144 |
| Wt% H2O | 32.54 | 26.72 | 47.20 | 34.55 |

