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. Author manuscript; available in PMC: 2013 Mar 26.
Published in final edited form as: J Org Chem. 2011 May 19;76(12):5061–5073. doi: 10.1021/jo200746y

Table 5.

Olefin CM Reactions in 2.5% aqueous PTSa

entry substrate olefinic partner product yield (%)b
1 graphic file with name nihms298140t1.jpg graphic file with name nihms298140t2.jpg graphic file with name nihms298140t3.jpg 92
2 graphic file with name nihms298140t4.jpg graphic file with name nihms298140t5.jpg graphic file with name nihms298140t6.jpg 97
3 graphic file with name nihms298140t7.jpg graphic file with name nihms298140t8.jpg graphic file with name nihms298140t9.jpg 84
4 graphic file with name nihms298140t10.jpg graphic file with name nihms298140t11.jpg graphic file with name nihms298140t12.jpg 88
5 graphic file with name nihms298140t13.jpg graphic file with name nihms298140t14.jpg graphic file with name nihms298140t15.jpg 90c (55)d
6 graphic file with name nihms298140t16.jpg graphic file with name nihms298140t17.jpg graphic file with name nihms298140t18.jpg 88
7 graphic file with name nihms298140t19.jpg graphic file with name nihms298140t20.jpg graphic file with name nihms298140t21.jpg 83c (50)d
8 graphic file with name nihms298140t22.jpg graphic file with name nihms298140t23.jpg graphic file with name nihms298140t24.jpg 84, 86f (tBu)
82(Et)
9 graphic file with name nihms298140t25.jpg graphic file with name nihms298140t26.jpg graphic file with name nihms298140t27.jpg 80 (tBu)
78(2-ethylhexyl)
a

Reaction were conducted at 0.5 M over 12 h at 22 °C using 3 mol % Grubbs-2.

b

Chromatographically pure materials.

c

Based on recovered starting material.

d

Isolated.

e

Mixture of cis and trans isomers.

f

Reaction run in 3 M aqueous NaCl/PTS for 6 h.