Table 2.
Effect of varying p-toluenesulfonamide (TsNH2or PTS) on the rate of reaction at 300 Ka
| 103 [PTS] | 104k/ (s-1) | |
|---|---|---|
| (mol dm-3) | [IMP] | [CLM] |
| 2.0 | 7.24 | 4.03 |
| 4.0 | 5.24 | 3.42 |
| 5.0 | 4.79 | 2.86 |
| 8.0 | 3.98 | 1.94 |
a[CAT]o = 2.0 x 10-4 mol dm-3; [Substrate]o= 4.0 x 10-3 mol dm-3;[HClO4] = 2.9 x 10-3 mol dm-3.