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. 2013 Apr 1;8(4):e60026. doi: 10.1371/journal.pone.0060026

Figure 1. Proposed oxidization of a methyl group at the C7 position of BChlide c to a formyl group in BChl e biosynthesis:

Figure 1

(i) monooxygenation of the 7-methyl to 7-hydroxymethyl group; (ii) monooxygenation of the 7-hydroxymethyl to 7-dihydroxymethyl group followed by the spontaneous dehydration to the 7-formyl group or direct dehydrogenation of the 7-hydroxymethyl to 7-formyl group. The C31-stereochemistry is R or S; R1 =  ethyl, propyl, or isobutyl; R2 =  methyl or ethyl.