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. Author manuscript; available in PMC: 2014 Feb 27.
Published in final edited form as: J Am Chem Soc. 2013 Feb 14;135(8):3286–3299. doi: 10.1021/ja400183g

Scheme 2.

Scheme 2

Schematics of the transition states (TS) of HS and LS FeIII–OOH in H-atom abstraction reaction. HS TS features shorter O–O and longer C–H bonds than those of the LS TS. Bond lengths are in Å.