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. Author manuscript; available in PMC: 2014 Feb 15.
Published in final edited form as: J Org Chem. 2013 Feb 6;78(4):1682–1686. doi: 10.1021/jo302638v

Table 1.

Scope of the TBHP-Mediated Wacker Oxidation graphic file with name nihms-443678-t0006.jpg

Entry substrate Product % Yield
1 graphic file with name nihms-443678-t0007.jpg graphic file with name nihms-443678-t0008.jpg 71
2 graphic file with name nihms-443678-t0009.jpg graphic file with name nihms-443678-t0010.jpg 76
3 graphic file with name nihms-443678-t0011.jpg graphic file with name nihms-443678-t0012.jpg 48
4 graphic file with name nihms-443678-t0013.jpg graphic file with name nihms-443678-t0014.jpg 68
5 graphic file with name nihms-443678-t0015.jpg graphic file with name nihms-443678-t0016.jpg 61
6 graphic file with name nihms-443678-t0017.jpg graphic file with name nihms-443678-t0018.jpg 93
7 graphic file with name nihms-443678-t0019.jpg graphic file with name nihms-443678-t0020.jpg 57
8 graphic file with name nihms-443678-t0021.jpg graphic file with name nihms-443678-t0022.jpg 66
9 graphic file with name nihms-443678-t0023.jpg graphic file with name nihms-443678-t0024.jpg 79
10 graphic file with name nihms-443678-t0025.jpg graphic file with name nihms-443678-t0026.jpg 31(59)a
11 graphic file with name nihms-443678-t0027.jpg graphic file with name nihms-443678-t0028.jpg <1
12 graphic file with name nihms-443678-t0029.jpg graphic file with name nihms-443678-t0030.jpg <1

All yields represent an average of two experiments on at least 0.5 mmol scale.

a

10 mol% Pd(Quinox)Cl2 and 25 mol% AgSbF6.