Table 3.
No. | Reaction | ΔE (gas) | ΔE (H2O) |
---|---|---|---|
1 | HNO+H2O→NH(OH)2 | 7.6 | 8.0 |
2 | HNO+CH3OH→NH(OH)(OCH3) | 3.0 | 2.6 |
3 | HNO+CH3NH2→NH(OH)(NHCH3) | −9.2 | −10.0 |
4 | HNO+CH3SH→NH(OH)(SCH3) | −20.8 | −17.5 |
5 | HNO+HNO→NH(OH)(NO) | −37.4 | −40.0 |
6 | HNO+3NO− →NH(NO)O− | −50.3 | −39.6 |